Synthesis of 4-(trifluoromethyl) coumarins using nano sulfated-titania as solid acid catalyst under solvent-free conditions
نویسندگان
چکیده مقاله:
Nano sulfated titania was tested as solid acid heterogeneous catalyst for the synthesis of 4-(Trifluoromethyl) coumarin and coumarin derivatives under solvent-free condition. Factorial design evidenced a positive effect of reaction temperature, amount of catalyst, and solvents. This nano-sized sulfated titania has been prepared by a sol-gel hydrothermal process. The prepared sulfated titania showed high catalytic activity in the synthesis of 4-(Trifluoromethyl) coumarin and coumarin derivatives. This method is of great value because of its environmentally benign character, easy handling, high yields, convenient operation, and green. FT-IR studies show that the catalyst can be reused for acylation without loss of catalytic activity.
منابع مشابه
synthesis of 4-(trifluoromethyl) coumarins using nano sulfated-titania as solid acid catalyst under solvent-free conditions
nano sulfated titania was tested as solid acid heterogeneous catalyst for the synthesis of 4-(trifluoromethyl) coumarin and coumarin derivatives under solvent-free condition. factorial design evidenced a positive effect of reaction temperature, amount of catalyst, and solvents. this nano-sized sulfated titania has been prepared by a sol-gel hydrothermal process. the prepared sulfated titania s...
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عنوان ژورنال
دوره 6 شماره 5
صفحات 423- 430
تاریخ انتشار 2016-12-01
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